732-329-3499 SGS TNI LABORATORY 1 of 11 JD3794 Dayton, NJ ## Dayton, NJ The results set forth herein are provided by SGS North America Inc. Technical Report for ## Technical Report for Providence Engineering Sampling Date: 02/20/20 ## Providence Engineering Valero-CAMS, Baton Rouge, LA 712-001 SGS Job Number: JD3794 Sampling Date: 02/20/20 Renort to. ## Report to Providence Engineering ATTN: Kevin Calhoun Total number of pages in report: 11 03/30/20 03/30/20 e-Hardcopy 2.0 Automated Report Test results contained within this data package meet the requirements of the National Environmental Laboratory Accreditation Program and/or state specific certification programs as applicable. Laura Degenhardt General Manager Client Service contact: Victoria Pushkova 732-329-0200 Certifications: NJ(12129), NY(10983), CA, CT, FL, IL, IN, KS, KY, LA, MA, MD, ME, MN, NC, OH VAP (CL0056), AK (UST-103), AZ (AZ0786), PA, RI, SC, TX, UT, VA, WV, DoD ELAP (ANAB L2248) This report shall not be reproduced, except in its entirety, without the written approval of SGS. Test results relate only to samples analyzed. SGS North America Inc. · 2235 Route 130 · Dayton, NJ 08810 · tel: 732-329-0200 · fax: 732-329-3499 SGS det ## Table of Contents -1- | Section 1: Sample Summary ................................................................................................... | 3 | | ----------------------------------------------------------------------------------------------------------------------------------- | --- | | Section 2: Sample Results ........................................................................................................ | 4 | | 2.1: JD3794-1: CAMS 519 .................................................................................................. | 5 | | Section 3: Misc. Forms ............................................................................................................ | 8 | | 3.1: Chain of Custody ........................................................................................................... | 9 | | 3.2: Summa Canister and Flow Controller Log .................................................................... | | 11 1 JD3794 ## Providence Engineering Valero-CAMS, Baton Rouge, LA Project No: 712-001 | Sample | Collected | Collected | Matrix | Matrix | Client | | ------------------------------------------------------------------------------------------------------------------------- | ------------------------------------------------------------------------------------------------------------------------- | ------------------------------------------------------------------------------------------------------------------------- | ------------------------------------------------------------------------------------------------------------------------- | ------------------------------------------------------------------------------------------------------------------------- | ------------------------------------------------------------------------------------------------------------------------- | | Number | Date | Time By | Received | Code Type | Sample ID | | This report contains results reported as ND =Not detected. The following applies: Organics ND =Not detected above the MDL | This report contains results reported as ND =Not detected. The following applies: Organics ND =Not detected above the MDL | This report contains results reported as ND =Not detected. The following applies: Organics ND =Not detected above the MDL | This report contains results reported as ND =Not detected. The following applies: Organics ND =Not detected above the MDL | This report contains results reported as ND =Not detected. The following applies: Organics ND =Not detected above the MDL | This report contains results reported as ND =Not detected. The following applies: Organics ND =Not detected above the MDL | | JD3794-1 | 02/20/20 | 10:40 BK | 02/27/20 | AIR Ambient Air Comp. | CAMS 519 | ## Sample Summary Job No: JD3794 SGS 4 of 11 JD3794 SGS LabLink@1069213 13:40 30-Mar-2020 ## Sample Results Report of Analysis ## Section 2 ## Report of Analysis Client Sample ID: CAMS 519 Lab Sample ID: JD3794-1 Date Sampled: 02/20/20 Matrix: AIR - Ambient Air Comp. Summa ID: A990 Date Received: 02/27/20 Method: TO-15 Percent Solids: n/a Project: Valero-CAMS, Baton Rouge, LA | | File ID | DF | Analyzed | By | Prep Date | Prep Batch | Analytical Batch | | ------ | --------- | --- | -------------- | --- | --------- | ---------- | ---------------- | | Run #1 | 6W16456.D | 1 | 03/04/20 20:49 | TCH | n/a | n/a | V6W688 | | Run #2 | 6W16493.D | 1 | 03/06/20 06:57 | TCH | n/a | n/a | V6W689 | ## Initial Volume Run #1 400 ml Run #2 100 ml ## VOA TO15 List | CAS No. | MW | Compound | Result | RL | MDL | Units | Q | Result RL | MDL | Units | | ---------- | ----- | -------------------------- | ------ | --- | ------ | ----- | ---- | --------- | ----- | ----- | | 67-64-1 | 58.08 | Acetone | 10.1 | 0.2 | 0.11 | ppbv | 24.0 | 0.48 | 0.26 | ug/m3 | | 106-99-0 | 54.09 | 1,3-Butadiene | ND | 0.2 | 0.046 | ppbv | ND | 0.44 | 0.1 | ug/m3 | | 71-43-2 | 78.11 | Benzene | 0.20 | 0.2 | 0.012 | ppbv | 0.64 | 0.64 | 0.038 | ug/m3 | | 75-27-4 | 163.8 | Bromodichloromethane | ND | 0.2 | 0.027 | ppbv | ND | 1.3 | 0.18 | ug/m3 | | 75-25-2 | 252.8 | Bromoform | ND | 0.2 | 0.037 | ppbv | ND | 2.1 | 0.38 | ug/m3 | | 74-83-9 | 94.94 | Bromomethane | ND | 0.2 | 0.022 | ppbv | ND | 0.78 | 0.085 | ug/m3 | | 593-60-2 | 106.9 | Bromoethene | ND | 0.2 | 0.022 | ppbv | ND | 0.87 | 0.096 | ug/m3 | | 100-44-7 | 126 | Benzyl Chloride | ND | 0.2 | 0.057 | ppbv | ND | 1 | 0.29 | ug/m3 | | 75-15-0 | 76.14 | Carbon disulfide | ND | 0.2 | 0.024 | ppbv | ND | 0.62 | 0.075 | ug/m3 | | 108-90-7 | 112.6 | Chlorobenzene | ND | 0.2 | 0.026 | ppbv | ND | 0.92 | 0.12 | ug/m3 | | 75-00-3 | 64.52 | Chloroethane | ND | 0.2 | 0.048 | ppbv | ND | 0.53 | 0.13 | ug/m3 | | 67-66-3 | 119.4 | Chloroform | ND | 0.2 | 0.02 | ppbv | ND | 0.98 | 0.098 | ug/m3 | | 74-87-3 | 50.49 | Chloromethane | 0.75 | 0.2 | 0.015 | ppbv | 1.5 | 0.41 | 0.031 | ug/m3 | | 107-05-1 | 76.53 | 3-Chloropropene | ND | 0.2 | 0.04 | ppbv | ND | 0.63 | 0.13 | ug/m3 | | 95-49-8 | 126.6 | 2-Chlorotoluene | ND | 0.2 | 0.025 | ppbv | ND | 1 | 0.13 | ug/m3 | | 56-23-5 | 153.8 | Carbon tetrachloride | ND | 0.2 | 0.024 | ppbv | ND | 1.3 | 0.15 | ug/m3 | | 110-82-7 | 84.16 | Cyclohexane | 1.5 | 0.2 | 0.022 | ppbv | 5.2 | 0.69 | 0.076 | ug/m3 | | 75-34-3 | 98.96 | 1,1-Dichloroethane | ND | 0.2 | 0.012 | ppbv | ND | 0.81 | 0.049 | ug/m3 | | 75-35-4 | 96.94 | 1,1-Dichloroethylene | ND | 0.2 | 0.017 | ppbv | ND | 0.79 | 0.067 | ug/m3 | | 106-93-4 | 187.9 | 1,2-Dibromoethane | ND | 0.2 | 0.018 | ppbv | ND | 1.5 | 0.14 | ug/m3 | | 107-06-2 | 98.96 | 1,2-Dichloroethane | ND | 0.2 | 0.021 | ppbv | ND | 0.81 | 0.085 | ug/m3 | | 78-87-5 | 113 | 1,2-Dichloropropane | ND | 0.2 | 0.019 | ppbv | ND | 0.92 | 0.088 | ug/m3 | | 123-91-1 | 88.12 | 1,4-Dioxane | ND | 0.2 | 0.052 | ppbv | ND | 0.72 | 0.19 | ug/m3 | | 75-71-8 | 120.9 | Dichlorodifluoromethane | 0.48 | 0.2 | 0.017 | ppbv | 2.4 | 0.99 | 0.084 | ug/m3 | | 124-48-1 | 208.3 | Dibromochloromethane | ND | 0.2 | 0.033 | ppbv | ND | 1.7 | 0.28 | ug/m3 | | 156-60-5 | 96.94 | trans-1,2-Dichloroethylene | ND | 0.2 | 0.0073 | ppbv | ND | 0.79 | 0.029 | ug/m3 | | 156-59-2 | 96.94 | cis-1,2-Dichloroethylene | ND | 0.2 | 0.012 | ppbv | ND | 0.79 | 0.048 | ug/m3 | | 10061-01-5 | 111 | cis-1,3-Dichloropropene | ND | 0.2 | 0.02 | ppbv | ND | 0.91 | 0.091 | ug/m3 | | 541-73-1 | 147 | m-Dichlorobenzene | ND | 0.2 | 0.019 | ppbv | ND | 1.2 | 0.11 | ug/m3 | | 95-50-1 | 147 | o-Dichlorobenzene | ND | 0.2 | 0.022 | ppbv | ND | 1.2 | 0.13 | ug/m3 | | 106-46-7 | 147 | p-Dichlorobenzene | ND | 0.2 | 0.018 | ppbv | ND | 1.2 | 0.11 | ug/m3 | | 10061-02-6 | 111 | trans-1,3-Dichloropropene | ND | 0.2 | 0.02 | ppbv | ND | 0.91 | 0.091 | ug/m3 | ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value RL = Reporting Limit B = Indicates analyte found in associated method blank E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound ## Report of Analysis Client Sample ID: CAMS 519 Lab Sample ID: JD3794-1 Date Sampled: 02/20/20 Matrix: AIR - Ambient Air Comp. Summa ID: A990 Date Received: 02/27/20 Method: TO-15 Percent Solids: n/a Project: Valero-CAMS, Baton Rouge, LA ## VOA TO15 List | CAS No. | MW | Compound | Result | RL | MDL | Units | Q | Result | RL | MDL | Units | | ----------------- | ----------- | ------------------------- | --------- | --------- | ----------- | --------- | --- | -------- | --------- | ---------- | ----------- | | 64-17-5 | 46.07 | Ethanol | 4.1 | 0.50 | 0.22 | ppbv | | 7.7 | 0.94 | 0.41 | ug/m3 | | 100-41-4 | 106.2 | Ethylbenzene | ND | 0.20 | 0.015 | ppbv | | ND | 0.87 | 0.065 | ug/m3 | | 141-78-6 | 88 | Ethyl Acetate | 0.11 | 0.20 | 0.038 | ppbv | J | 0.40 | 0.72 | 0.14 | ug/m3 | | 622-96-8 | 120.2 | 4-Ethyltoluene | ND | 0.20 | 0.030 | ppbv | | ND | 0.98 | 0.15 | ug/m3 | | 76-13-1 | 187.4 | Freon 113 | ND | 0.20 | 0.017 | ppbv | | ND | 1.5 | 0.13 | ug/m3 | | 76-14-2 | 170.9 | Freon 114 | ND | 0.20 | 0.019 | ppbv | | ND | 1.4 | 0.13 | ug/m3 | | 142-82-5 | 100.2 | Heptane | 0.14 | 0.20 | 0.018 | ppbv | J | 0.57 | 0.82 | 0.074 | ug/m3 | | 87-68-3 | 260.8 | Hexachlorobutadiene | ND | 0.20 | 0.046 | ppbv | | ND | 2.1 | 0.49 | ug/m3 | | 110-54-3 | 86.17 | Hexane | 19.1 | 0.20 | 0.011 | ppbv | | 67.3 | 0.70 | 0.039 | ug/m3 | | 591-78-6 | 100 | 2-Hexanone | ND | 0.20 | 0.036 | ppbv | | ND | 0.82 | 0.15 | ug/m3 | | 67-63-0 | 60.1 | Isopropyl Alcohol | 0.60 | 0.20 | 0.065 | ppbv | | 1.5 | 0.49 | 0.16 | ug/m3 | | 75-09-2 | 84.94 | Methylene chloride | 1.4 | 0.20 | 0.015 | ppbv | | 4.9 | 0.69 | 0.052 | ug/m3 | | 78-93-3 | 72.11 | Methyl ethyl ketone | 59.2 a | 0.80 | 0.17 | ppbv | | 175 a | 2.4 | 0.50 | ug/m3 | | 108-10-1 | 100.2 | Methyl Isobutyl Ketone | 40.8 a | 0.80 | 0.14 | ppbv | | 167 a | 3.3 | 0.57 | ug/m3 | | 1634-04-4 | 88.15 | Methyl Tert Butyl Ether | ND | 0.20 | 0.019 | ppbv | | ND | 0.72 | 0.069 | ug/m3 | | 80-62-6 | 100.12 | Methylmethacrylate | ND | 0.20 | 0.033 | ppbv | | ND | 0.82 | 0.14 | ug/m3 | | 115-07-1 | 42 | Propylene | ND | 0.50 | 0.016 | ppbv | | ND | 0.86 | 0.027 | ug/m3 | | 100-42-5 | 104.1 | Styrene | ND | 0.20 | 0.019 | ppbv | | ND | 0.85 | 0.081 | ug/m3 | | 71-55-6 | 133.4 | 1,1,1-Trichloroethane | ND | 0.20 | 0.033 | ppbv | | ND | 1.1 | 0.18 | ug/m3 | | 79-34-5 | 167.9 | 1,1,2,2-Tetrachloroethane | ND | 0.20 | 0.027 | ppbv | | ND | 1.4 | 0.19 | ug/m3 | | 79-00-5 | 133.4 | 1,1,2-Trichloroethane | ND | 0.20 | 0.030 | ppbv | | ND | 1.1 | 0.16 | ug/m3 | | 120-82-1 | 181.5 | 1,2,4-Trichlorobenzene | ND | 0.20 | 0.089 | ppbv | | ND | 1.5 | 0.66 | ug/m3 | | 95-63-6 | 120.2 | 1,2,4-Trimethylbenzene | ND | 0.20 | 0.033 | ppbv | | ND | 0.98 | 0.16 | ug/m3 | | 108-67-8 | 120.2 | 1,3,5-Trimethylbenzene | ND | 0.20 | 0.034 | ppbv | | ND | 0.98 | 0.17 | ug/m3 | | 540-84-1 | 114.2 | 2,2,4-Trimethylpentane | ND | 0.20 | 0.022 | ppbv | | ND | 0.93 | 0.10 | ug/m3 | | 75-65-0 | 74.12 | Tertiary Butyl Alcohol | 0.18 | 0.20 | 0.014 | ppbv | J | 0.55 | 0.61 | 0.042 | ug/m3 | | 127-18-4 | 165.8 | Tetrachloroethylene | ND | 0.040 | 0.031 | ppbv | | ND | 0.27 | 0.21 | ug/m3 | | 109-99-9 | 72.11 | Tetrahydrofuran | ND | 0.20 | 0.050 | ppbv | | ND | 0.59 | 0.15 | ug/m3 | | 108-88-3 | 92.14 | Toluene | 72.5 a | 0.80 | 0.058 | ppbv | | 273 a | 3.0 | 0.22 | ug/m3 | | 79-01-6 | 131.4 | Trichloroethylene | 0.037 | 0.040 | 0.019 | ppbv | J | 0.20 | 0.21 | 0.10 | ug/m3 | | 75-69-4 | 137.4 | Trichlorofluoromethane | 0.24 | 0.20 | 0.028 | ppbv | | 1.3 | 1.1 | 0.16 | ug/m3 | | 75-01-4 | 62.5 | Vinyl chloride | ND | 0.20 | 0.022 | ppbv | | ND | 0.51 | 0.056 | ug/m3 | | 108-05-4 | 86 | Vinyl Acetate | ND | 0.20 | 0.034 | ppbv | | ND | 0.70 | 0.12 0.074 | ug/m3 ug/m3 | | | 106.2 | m,p-Xylene | 0.36 | 0.20 | 0.034 | ppbv | | 1.6 | 0.87 | 0.15 | ug/m3 | | 95-47-6 1330-20-7 | 106.2 106.2 | o-Xylene Xylenes (total) | 0.17 0.53 | 0.20 0.20 | 0.017 0.017 | ppbv ppbv | J | 0.74 2.3 | 0.87 0.87 | 0.074 | ug/m3 | CAS No. Surrogate Recoveries Run# 1 Run# 2 Limits 460-00-4 4-Bromofluorobenzene 96% 90% 65-128% ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value RL = Reporting Limit B = Indicates analyte found in associated method blank E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound JD3794 ## Report of Analysis Client Sample ID: CAMS 519 Lab Sample ID: JD3794-1 Date Sampled: 02/20/20 Matrix: AIR - Ambient Air Comp. Summa ID: A990 Date Received: 02/27/20 Method: TO-15 Percent Solids: n/a Project: Valero-CAMS, Baton Rouge, LA ## VOA TO15 List CAS No. MW Compound Result RL MDL Units Q Result RL MDL Units (a) Result is from Run# 2 E = Indicates value exceeds calibration range J = Indicates an estimated value B = Indicates analyte found in associated method blank N = Indicates presumptive evidence of a compound SGS 8 of 11 JD3794 SGS LabLink@1069213 13:40 30-Mar-2020 ## Misc. Forms ## Custody Documents and Other Forms ## Includes the following where applicable - Chain of Custody - Summa Canister and Flow Controller Log SGS 9 of 11 JD3794 JD3794: Chain of Custody Page 1 of 2 JD3794 ## SGS Sample Receipt Summary Job Number: JD3794 Client: PROVIDENCE ENG Date / Time Received: 2/27/2020 10:45:00 AM Delivery Method: Project: PROVIDENCE - CAMS 4. No. Coolers: N/A Airbill #'s: ## Cooler Security 1. Custody Seals Present: Y or N 2. Custody Seals Intact: 3. COC Present: 4. Smpl Dates/Time OK 5. Cooler temp verification: ## Cooler Temperature Y or N 1. Temp criteria achieved: 2. Cooler media: N/A N/A ## Quality Control Preservation Y or N N/A 1. Trip Blank present / cooler: 2. Trip Blank listed on COC: 3. Samples preserved properly: 4. VOCs headspace free: ## Sample Integrity - Documentation Y or N 1. Sample labels present on bottles: 2. Container labeling complete: 3. Sample container label / COC agree: ## Sample Integrity - Condition Y or N 1. Sample recvd within HT: 2. Condition of sample: 3. All containers accounted for: ## Sample Integrity - Instructions 1. Analysis requested is clear: 2. Bottles received for unspecified tests 3. Sufficient volume recvd for analysis: 4. Compositing instructions clear: 5. Filtering instructions clear: Intact Y or N Comments Y or N N/A Cooler Temps (Raw Measured) °C: Cooler Temps (Corrected) °C: Test Strip Lot #s: pH 1-12: 229517 pH 12+: 208717 Other: (Specify) SM089-03 Rev. Date 12/7/17 JD3794: Chain of Custody Page 2 of 2 Job Number: JD3794 Account: PROVLABR Providence Engineering Project: Valero-CAMS, Baton Rouge, LA Received: 02/27/20 ## SGS Bottle Order(s) VP-012420-47 | Prep Date | Room Temp(F) | Bar Pres "Hg | | --------- | ------------ | ------------ | | 01/27/20 | 70 | 29.92 |