fil/tools/benchmark-harness/vendored/docling/md/pdfa_042.md

732-329-3499

SGS

TNI

LABORATORY

1 of 11

JD3794

Dayton, NJ

Dayton, NJ

The results set forth herein are provided by SGS North America Inc.

Technical Report for

Technical Report for

Providence Engineering

Sampling Date: 02/20/20

Providence Engineering

Valero-CAMS, Baton Rouge, LA

712-001

SGS Job Number: JD3794

Sampling Date: 02/20/20

Renort to.

Report to

Providence Engineering

kevincalhoun@providenceeng.com

ATTN: Kevin Calhoun

Total number of pages in report:

11

03/30/20

03/30/20

e-Hardcopy 2.0 Automated Report

Test results contained within this data package meet the requirements of the National Environmental Laboratory Accreditation Program and/or state specific certification programs as applicable.

Laura Degenhardt General Manager

Client Service contact: Victoria Pushkova 732-329-0200

Certifications: NJ(12129), NY(10983), CA, CT, FL, IL, IN, KS, KY, LA, MA, MD, ME, MN, NC, OH VAP (CL0056), AK (UST-103), AZ (AZ0786), PA, RI, SC, TX, UT, VA, WV, DoD ELAP (ANAB L2248)

This report shall not be reproduced, except in its entirety, without the written approval of SGS. Test results relate only to samples analyzed.

SGS North America Inc. · 2235 Route 130 · Dayton, NJ 08810 · tel: 732-329-0200 · fax: 732-329-3499

SGS

det

Table of Contents

-1-

Section 1: Sample Summary ...................................................................................................	3
Section 2: Sample Results ........................................................................................................	4
2.1: JD3794-1: CAMS 519 ..................................................................................................	5
Section 3: Misc. Forms ............................................................................................................	8
3.1: Chain of Custody ...........................................................................................................	9
3.2: Summa Canister and Flow Controller Log ....................................................................

11

1

JD3794

Providence Engineering

Valero-CAMS, Baton Rouge, LA Project No: 712-001

Sample	Collected	Collected	Matrix	Matrix	Client
Number	Date	Time By	Received	Code Type	Sample ID
This report contains results reported as ND =Not detected. The following applies: Organics ND =Not detected above the MDL	This report contains results reported as ND =Not detected. The following applies: Organics ND =Not detected above the MDL	This report contains results reported as ND =Not detected. The following applies: Organics ND =Not detected above the MDL	This report contains results reported as ND =Not detected. The following applies: Organics ND =Not detected above the MDL	This report contains results reported as ND =Not detected. The following applies: Organics ND =Not detected above the MDL	This report contains results reported as ND =Not detected. The following applies: Organics ND =Not detected above the MDL
JD3794-1	02/20/20	10:40 BK	02/27/20	AIR Ambient Air Comp.	CAMS 519

Sample Summary

Job No:

JD3794

SGS

4 of 11

JD3794

SGS LabLink@1069213 13:40 30-Mar-2020

Sample Results

Report of Analysis

Section 2

Report of Analysis

Client Sample ID:

CAMS 519

Lab Sample ID:

JD3794-1

Date Sampled:

02/20/20

Matrix:

AIR - Ambient Air Comp. Summa ID: A990

Date Received:

02/27/20

Method:

TO-15

Percent Solids:

n/a

Project:

Valero-CAMS, Baton Rouge, LA

	File ID	DF	Analyzed	By	Prep Date	Prep Batch	Analytical Batch
Run #1	6W16456.D	1	03/04/20 20:49	TCH	n/a	n/a	V6W688
Run #2	6W16493.D	1	03/06/20 06:57	TCH	n/a	n/a	V6W689

Initial Volume

Run #1

400 ml

Run #2

100 ml

VOA TO15 List

CAS No.	MW	Compound	Result	RL	MDL	Units	Q	Result RL	MDL	Units
67-64-1	58.08	Acetone	10.1	0.2	0.11	ppbv	24.0	0.48	0.26	ug/m3
106-99-0	54.09	1,3-Butadiene	ND	0.2	0.046	ppbv	ND	0.44	0.1	ug/m3
71-43-2	78.11	Benzene	0.20	0.2	0.012	ppbv	0.64	0.64	0.038	ug/m3
75-27-4	163.8	Bromodichloromethane	ND	0.2	0.027	ppbv	ND	1.3	0.18	ug/m3
75-25-2	252.8	Bromoform	ND	0.2	0.037	ppbv	ND	2.1	0.38	ug/m3
74-83-9	94.94	Bromomethane	ND	0.2	0.022	ppbv	ND	0.78	0.085	ug/m3
593-60-2	106.9	Bromoethene	ND	0.2	0.022	ppbv	ND	0.87	0.096	ug/m3
100-44-7	126	Benzyl Chloride	ND	0.2	0.057	ppbv	ND	1	0.29	ug/m3
75-15-0	76.14	Carbon disulfide	ND	0.2	0.024	ppbv	ND	0.62	0.075	ug/m3
108-90-7	112.6	Chlorobenzene	ND	0.2	0.026	ppbv	ND	0.92	0.12	ug/m3
75-00-3	64.52	Chloroethane	ND	0.2	0.048	ppbv	ND	0.53	0.13	ug/m3
67-66-3	119.4	Chloroform	ND	0.2	0.02	ppbv	ND	0.98	0.098	ug/m3
74-87-3	50.49	Chloromethane	0.75	0.2	0.015	ppbv	1.5	0.41	0.031	ug/m3
107-05-1	76.53	3-Chloropropene	ND	0.2	0.04	ppbv	ND	0.63	0.13	ug/m3
95-49-8	126.6	2-Chlorotoluene	ND	0.2	0.025	ppbv	ND	1	0.13	ug/m3
56-23-5	153.8	Carbon tetrachloride	ND	0.2	0.024	ppbv	ND	1.3	0.15	ug/m3
110-82-7	84.16	Cyclohexane	1.5	0.2	0.022	ppbv	5.2	0.69	0.076	ug/m3
75-34-3	98.96	1,1-Dichloroethane	ND	0.2	0.012	ppbv	ND	0.81	0.049	ug/m3
75-35-4	96.94	1,1-Dichloroethylene	ND	0.2	0.017	ppbv	ND	0.79	0.067	ug/m3
106-93-4	187.9	1,2-Dibromoethane	ND	0.2	0.018	ppbv	ND	1.5	0.14	ug/m3
107-06-2	98.96	1,2-Dichloroethane	ND	0.2	0.021	ppbv	ND	0.81	0.085	ug/m3
78-87-5	113	1,2-Dichloropropane	ND	0.2	0.019	ppbv	ND	0.92	0.088	ug/m3
123-91-1	88.12	1,4-Dioxane	ND	0.2	0.052	ppbv	ND	0.72	0.19	ug/m3
75-71-8	120.9	Dichlorodifluoromethane	0.48	0.2	0.017	ppbv	2.4	0.99	0.084	ug/m3
124-48-1	208.3	Dibromochloromethane	ND	0.2	0.033	ppbv	ND	1.7	0.28	ug/m3
156-60-5	96.94	trans-1,2-Dichloroethylene	ND	0.2	0.0073	ppbv	ND	0.79	0.029	ug/m3
156-59-2	96.94	cis-1,2-Dichloroethylene	ND	0.2	0.012	ppbv	ND	0.79	0.048	ug/m3
10061-01-5	111	cis-1,3-Dichloropropene	ND	0.2	0.02	ppbv	ND	0.91	0.091	ug/m3
541-73-1	147	m-Dichlorobenzene	ND	0.2	0.019	ppbv	ND	1.2	0.11	ug/m3
95-50-1	147	o-Dichlorobenzene	ND	0.2	0.022	ppbv	ND	1.2	0.13	ug/m3
106-46-7	147	p-Dichlorobenzene	ND	0.2	0.018	ppbv	ND	1.2	0.11	ug/m3
10061-02-6	111	trans-1,3-Dichloropropene	ND	0.2	0.02	ppbv	ND	0.91	0.091	ug/m3

ND = Not detected

MDL = Method Detection Limit

J = Indicates an estimated value

RL = Reporting Limit

B = Indicates analyte found in associated method blank

E = Indicates value exceeds calibration range

N = Indicates presumptive evidence of a compound

Report of Analysis

Client Sample ID:

CAMS 519

Lab Sample ID:

JD3794-1

Date Sampled:

02/20/20

Matrix:

AIR - Ambient Air Comp. Summa ID: A990

Date Received:

02/27/20

Method:

TO-15

Percent Solids:

n/a

Project:

Valero-CAMS, Baton Rouge, LA

VOA TO15 List

CAS No.	MW	Compound	Result	RL	MDL	Units	Q	Result	RL	MDL	Units
64-17-5	46.07	Ethanol	4.1	0.50	0.22	ppbv		7.7	0.94	0.41	ug/m3
100-41-4	106.2	Ethylbenzene	ND	0.20	0.015	ppbv		ND	0.87	0.065	ug/m3
141-78-6	88	Ethyl Acetate	0.11	0.20	0.038	ppbv	J	0.40	0.72	0.14	ug/m3
622-96-8	120.2	4-Ethyltoluene	ND	0.20	0.030	ppbv		ND	0.98	0.15	ug/m3
76-13-1	187.4	Freon 113	ND	0.20	0.017	ppbv		ND	1.5	0.13	ug/m3
76-14-2	170.9	Freon 114	ND	0.20	0.019	ppbv		ND	1.4	0.13	ug/m3
142-82-5	100.2	Heptane	0.14	0.20	0.018	ppbv	J	0.57	0.82	0.074	ug/m3
87-68-3	260.8	Hexachlorobutadiene	ND	0.20	0.046	ppbv		ND	2.1	0.49	ug/m3
110-54-3	86.17	Hexane	19.1	0.20	0.011	ppbv		67.3	0.70	0.039	ug/m3
591-78-6	100	2-Hexanone	ND	0.20	0.036	ppbv		ND	0.82	0.15	ug/m3
67-63-0	60.1	Isopropyl Alcohol	0.60	0.20	0.065	ppbv		1.5	0.49	0.16	ug/m3
75-09-2	84.94	Methylene chloride	1.4	0.20	0.015	ppbv		4.9	0.69	0.052	ug/m3
78-93-3	72.11	Methyl ethyl ketone	59.2 a	0.80	0.17	ppbv		175 a	2.4	0.50	ug/m3
108-10-1	100.2	Methyl Isobutyl Ketone	40.8 a	0.80	0.14	ppbv		167 a	3.3	0.57	ug/m3
1634-04-4	88.15	Methyl Tert Butyl Ether	ND	0.20	0.019	ppbv		ND	0.72	0.069	ug/m3
80-62-6	100.12	Methylmethacrylate	ND	0.20	0.033	ppbv		ND	0.82	0.14	ug/m3
115-07-1	42	Propylene	ND	0.50	0.016	ppbv		ND	0.86	0.027	ug/m3
100-42-5	104.1	Styrene	ND	0.20	0.019	ppbv		ND	0.85	0.081	ug/m3
71-55-6	133.4	1,1,1-Trichloroethane	ND	0.20	0.033	ppbv		ND	1.1	0.18	ug/m3
79-34-5	167.9	1,1,2,2-Tetrachloroethane	ND	0.20	0.027	ppbv		ND	1.4	0.19	ug/m3
79-00-5	133.4	1,1,2-Trichloroethane	ND	0.20	0.030	ppbv		ND	1.1	0.16	ug/m3
120-82-1	181.5	1,2,4-Trichlorobenzene	ND	0.20	0.089	ppbv		ND	1.5	0.66	ug/m3
95-63-6	120.2	1,2,4-Trimethylbenzene	ND	0.20	0.033	ppbv		ND	0.98	0.16	ug/m3
108-67-8	120.2	1,3,5-Trimethylbenzene	ND	0.20	0.034	ppbv		ND	0.98	0.17	ug/m3
540-84-1	114.2	2,2,4-Trimethylpentane	ND	0.20	0.022	ppbv		ND	0.93	0.10	ug/m3
75-65-0	74.12	Tertiary Butyl Alcohol	0.18	0.20	0.014	ppbv	J	0.55	0.61	0.042	ug/m3
127-18-4	165.8	Tetrachloroethylene	ND	0.040	0.031	ppbv		ND	0.27	0.21	ug/m3
109-99-9	72.11	Tetrahydrofuran	ND	0.20	0.050	ppbv		ND	0.59	0.15	ug/m3
108-88-3	92.14	Toluene	72.5 a	0.80	0.058	ppbv		273 a	3.0	0.22	ug/m3
79-01-6	131.4	Trichloroethylene	0.037	0.040	0.019	ppbv	J	0.20	0.21	0.10	ug/m3
75-69-4	137.4	Trichlorofluoromethane	0.24	0.20	0.028	ppbv		1.3	1.1	0.16	ug/m3
75-01-4	62.5	Vinyl chloride	ND	0.20	0.022	ppbv		ND	0.51	0.056	ug/m3
108-05-4	86	Vinyl Acetate	ND	0.20	0.034	ppbv		ND	0.70	0.12 0.074	ug/m3 ug/m3
	106.2	m,p-Xylene	0.36	0.20	0.034	ppbv		1.6	0.87	0.15	ug/m3
95-47-6 1330-20-7	106.2 106.2	o-Xylene Xylenes (total)	0.17 0.53	0.20 0.20	0.017 0.017	ppbv ppbv	J	0.74 2.3	0.87 0.87	0.074	ug/m3

CAS No.

Surrogate Recoveries

Run# 1

Run# 2

Limits

460-00-4

4-Bromofluorobenzene

96%

90%

65-128%

ND = Not detected

MDL = Method Detection Limit

J = Indicates an estimated value

RL = Reporting Limit

B = Indicates analyte found in associated method blank

E = Indicates value exceeds calibration range

N = Indicates presumptive evidence of a compound

JD3794

Report of Analysis

Client Sample ID:

CAMS 519

Lab Sample ID:

JD3794-1

Date Sampled:

02/20/20

Matrix:

AIR - Ambient Air Comp. Summa ID: A990

Date Received:

02/27/20

Method:

TO-15

Percent Solids:

n/a

Project:

Valero-CAMS, Baton Rouge, LA

VOA TO15 List

CAS No. MW

Compound

Result RL MDL Units Q Result RL MDL Units

(a) Result is from Run# 2

E = Indicates value exceeds calibration range

J = Indicates an estimated value

B = Indicates analyte found in associated method blank

N = Indicates presumptive evidence of a compound

SGS

8 of 11

JD3794

SGS LabLink@1069213 13:40 30-Mar-2020

Misc. Forms

Custody Documents and Other Forms

Includes the following where applicable

• Chain of Custody
• Summa Canister and Flow Controller Log

SGS

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JD3794

JD3794: Chain of Custody Page 1 of 2

JD3794

SGS Sample Receipt Summary

Job Number:

JD3794

Client:

PROVIDENCE ENG

Date / Time Received:

2/27/2020 10:45:00 AM

Delivery Method:

Project:

PROVIDENCE - CAMS

4. No. Coolers:

N/A

Airbill #'s:

Cooler Security

1. Custody Seals Present:

Y or N

2. Custody Seals Intact:

3. COC Present:

4. Smpl Dates/Time OK

5. Cooler temp verification:

Cooler Temperature

Y or N

1. Temp criteria achieved:

2. Cooler media:

N/A

N/A

Quality Control Preservation

Y or N N/A

1. Trip Blank present / cooler:

2. Trip Blank listed on COC:

3. Samples preserved properly:

4. VOCs headspace free:

Sample Integrity - Documentation

Y or N

1. Sample labels present on bottles:

2. Container labeling complete:

3. Sample container label / COC agree:

Sample Integrity - Condition

Y or N

1. Sample recvd within HT:

2. Condition of sample:

3. All containers accounted for:

Sample Integrity - Instructions

1. Analysis requested is clear:

2. Bottles received for unspecified tests

3. Sufficient volume recvd for analysis:

4. Compositing instructions clear:

5. Filtering instructions clear:

Intact

Y or N

Comments

Y or N N/A

Cooler Temps (Raw Measured) °C:

Cooler Temps (Corrected) °C:

Test Strip Lot #s:

pH 1-12:

229517

pH 12+:

208717

Other: (Specify)

SM089-03

Rev. Date 12/7/17

JD3794: Chain of Custody

Page 2 of 2

Job Number:

JD3794

Account:

PROVLABR Providence Engineering

Project:

Valero-CAMS, Baton Rouge, LA

Received:

02/27/20

SGS Bottle Order(s)

VP-012420-47

Prep Date	Room Temp(F)	Bar Pres "Hg
01/27/20	70	29.92